Solid-state sodium-ion batteries are far safer than conventional lithium-ion batteries, which pose a risk of fire and explosions, but their performance has been too weak to offset the safety advantages.
Researchers Friday reported developing an organic cathode that dramatically improves both stability and energy density.
The improved performance, reported in the journal Joule, is related to two key findings:
The resistive interface between the electrolyte and cathode that commonly forms during cycling can be reversed, extending cycle life, and
The flexibility of the organic cathode allowed it to maintain intimate contact at the interface with the solid electrolyte, even as the cathode expanded and contracted during cycling.
Yan Yao, associate professor of electrical and computer engineering at the University of Houston and corresponding author of the paper, said the organic cathode - known as PTO, for pyrene-4,5,9,10-tetraone - offers unique advantages over previous inorganic cathodes.