Designs for Cryogenic Tanks
Liquid-storage vessels
Liquid hydrogen (LH2) is typically stored in cylindrical tanks. Spherical tanks can carry a significant amount of liquid. Cryogenic tanks are vacuum insulated to minimize evaporation losses and contain redundant pressure release mechanisms to prevent over-pressurization. Liquid hydrogen tanks typically operate at pressures of up to 850 kPa (123 psi).
The pressure release system will function at a maximum pressure of 1,035 kPa (150 psi) in most tanks. Even if hydrogen is not drawn from the tank, LH2 evaporation will occur, and the resulting pressure will be released on a regular basis by the pressure relief mechanism as part of normal operation.
Cryogenic tanks are constructed and manufactured in accordance with well-established norms such as:
- The US Department of Transportation’s restrictions apply to transportable storage tanks.
- Transport Canada imposes limitations on mobile storage tanks.
- Regulations such as the ASME Boiler and Pressure Vessel Code (BPVC) apply to stationary storage tanks.
- Larger tanks are occasionally designed in line with standards such as API Standard 620, Design and Construction of Large, Welded, Low-Pressure Storage Tanks.
- Stationary tank supports should be able to resist fire exposure without failing.
The paperwork for each vessel should include a description of the vessel, a list of available drawings or other materials, the most recent inspection results, and the name of the responsible person. Vessels must also be marked in accordance with the applicable regulations. Each cryogenic liquid storage tank (stationary and mobile) should be legibly labeled “LIQUEFIED HYDROGEN – FLAMMABLE GAS.”
A warning labeled “Do not spray water on or into the vent hole” should be displayed on the vessel near the pressure-relief valve vent stack. Local first responders and firefighters should be specially trained in LH2 spill response tactics.
Cryogenic liquids and the containers in which they are stored
Cryogenic tanks are used to safeguard cryogenic liquids. Cryogenic liquids are liquefied gases that have temperatures of -150 °C or below. Byproducts include oxygen, argon, nitrogen, hydrogen, and helium. Cryogenic tanks may also be used to store gases at higher temperatures, such as LNG, carbon dioxide, and nitrous oxide. These are components of gas supply systems used in a number of sectors including metal processing, medical technology, electronics, water treatment, energy generation, and food processing. Low temperature chilling uses using cryogenic liquids include engineering shrink fitting, food freezing, and bio-sample storage.
Cryogenic tanks are thermally insulated and are typically equipped with a vacuum jacket. They are created and manufactured to stringent standards in compliance with international design criteria. They might be fixed, movable, or transportable.
Static cryogenic tanks are designed for permanent usage; however, transportable small tanks on wheels for use in workshops and laboratories are provided. Because static cryogenic tanks are typically classified as pressure vessels, new tanks and their associated systems will be built and installed in accordance with the Pressure Equipment (Safety) Regulations. For applications requiring direct access to the liquid, non-pressurized open neck vessels (Dewar flasks) are also available. The tanks are available in a range of sizes, pressures, and flow rates to meet the different demands of the customers. Tanks used to transport cryogenic liquids must comply with the Regulations on the Carriage of Dangerous Goods and the Use of Transportable Pressure Equipment.
Use, operation, maintenance, and disposal of cryogenic tanks
All applicable regulations, such as the Pressure Systems Safety Regulations for static tanks and the Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations for transportable tanks, must be followed when operating and maintaining cryogenic tanks. Cryogenic tanks must be maintained and operated by trained personnel.
The Regulations require cryogenic tanks to be inspected on a regular basis, as well as routinely maintained and subjected to formal examinations on a periodic basis for static tanks. To ensure that the tank is in safe operating condition between official examination times, an inspection and maintenance program should be created. This will include a Written Plan of Examination, which will be created by a competent person(s), as well as periodic formal examinations conducted in accordance with the scheme.
Transportable tanks must be inspected and tested on a regular basis, which may only be done by an Inspection Body recognized by the National Competent Authority, Department for Transport, in the United Kingdom (DfT). The Vehicle Certification Agency (VCA) website provides information on Examination Bodies that have been assigned to execute various tasks relating to tank and/or pressure equipment inspection. All inspections, examinations, and tests are documented, and these documents must be kept for the duration of the tank’s life.
Cryogenic tank users and owners have legal obligations as well as a duty of care to ensure that their equipment is properly maintained and operated. The user must undertake routine safety inspections. Daily inspections must be carried out. A gas company will only fill a tank if it believes it is safe to do so. While in use, a small amount of icing and ice may be visible. Small levels of ice are not cause for concern, but the quantity of ice should be checked on a frequent basis. To minimize excessive ice collection, de-icing should be conducted if ice continues to accumulate.
Cryogenic tank repair and modification
Any repair or modification to a cryogenic tank should be performed only by a skilled repairer in accordance with the design codes to which it was constructed, while taking current regulations and legislation into account. Such repairs or adjustments must not affect the structural integrity or the operation of any protective systems. All repairs and adjustments must be documented, and the documentation must be kept for the rest of the tank’s life.
Cryogenic tank revalidation
Cryogenic tanks must be assessed on a regular basis to ensure that they are safe to use. The revalidation period, which shall not exceed 20 years, shall be determined by a Competent Person. Mobile tanks should be rented for a shorter period of time due to the nature of their function. When a tank is revalidated, a report is created that must be kept with the tank data for the life of the tank.
Security for Cryogenic Tanks
Liquid oxygen, liquid nitrogen, and liquid argon are examples of cryogenic liquids. Their respective boiling points are as follows:
- -297.3oF | -183oC • -320.4°F | -195.8°C
- Liquid Oxygen Nitrogen in liquid form
- -302.6°F (-185.9°C) Argon Liquid
- The sublimation point of liquid CO2 is -109.3°F | -78.5°C.
To prevent heat transfer and sustain very low temperatures, the storage vessel must be correctly constructed. The water capacity of commercially available liquid oxygen, liquid nitrogen, and liquid argon storage tanks ranges from 350 to 13,000 US gallons (1,325 to 49,210 liters). The storage tanks for Cryogenic Bulk Tanks may be vertical, spherical, or horizontal, depending on the location and consumption demands.
Cryogenic liquid storage tanks are made up of three major components:
• Vessel of Internal Pressure
A cryogenic vessel made of stainless steel or other materials with high strength when exposed to cryogenic temperatures.
• The Outer Vessel
A vessel made of carbon steel or stainless steel. Under normal operating conditions, this vessel maintains the insulation around the inner pressure vessel and can also maintain a vacuum around the inner vessel. Most of the time, the external vessel is not exposed to cryogenic temperatures.
• Insulation
The vacuum-sealed space between the inner and outer vessels, which is filled with several inches of insulating material. The vacuum and insulating material help to reduce heat transfer and, as a consequence, the boil-off of the liquid oxygen, liquid nitrogen, or liquid argon contained inside the vessel.
The inner vessel of a storage tank is typically designed to sustain a maximum allowed operating pressure of 250 psig (1724 kPa). Vessels may be designed for higher or lower working pressures, as well as for specific uses. The service pressure of the vessel may be adjusted.
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